Process and apparatus for manufacturing lithium or lithium alloy thin sheets for electrochemical cells

ABSTRACT

A method of manufacturing lithium or lithium alloy anodes for electrochemical cells by an extrusion process wherein a lithium or lithium alloy ingot is formed into a thin sheet. The method is adapted to extrude thin sheet having a width exceeding the diameter of the lithium or lithium alloy ingot and enables the extrusion of lithium or lithium alloy thin sheets with more than one lithium or lithium alloy ingot. The invention also provides a die assembly adapted to allow adjustment and fine tuning of a die aperture while the extrusion process of a lithium or lithium alloy ingot is being carried out.

CROSS-REFERENCE TO RELATED APPLICATION

The present application is a divisional application of U.S. applicationSer. No. 10/172,020 filed on Jun. 17, 2002, now issued as U.S. Pat. No.6,854,312.

FIELD OF THE INVENTION

The present invention generally relates to lithium metal polymerbatteries and, more specifically, to a process for producing the lithiumor lithium alloy anode components of electrochemical (EC) cells. Theinvention also concerns an apparatus for producing the lithium/lithiumalloy anode components.

BACKGROUND OF THE INVENTION

Rechargeable batteries, which are manufactured from laminates of solidpolymer electrolytes interposed between sheet-like electrodes, displaymany advantages over conventional liquid electrolyte batteries. Theseadvantages typically include: lower overall battery weight; higher powerdensity; higher specific energy; and longer service life. In addition,such batteries are also more environmentally friendly since the dangerof spilling toxic liquid into the environment is eliminated.

EC cells generally include the following components: positiveelectrodes; negative electrodes; and an insulating material capable ofpermitting ionic conductivity, such as a solid polymer electrolyte,sandwiched between the electrodes. The negative electrodes, which arecommonly referred to as anodes, are usually made of light-weightmetallic foils, such as alkali metals and alloys, typically lithiummetal, lithium-aluminum alloys and the like. The positive electrodes,which are commonly referred to as cathodes, are usually formed of acomposite mixture of: an active material such as a transitional metaloxide; an electrically conductive filler, usually carbon particles; anionically conductive polymer electrolyte material; and a currentcollecting element, usually a thin sheet of aluminum. Composite cathodethin films are usually obtained by coating the composite mixture onto acurrent collector.

Since solid polymer electrolytes are less conductive than liquid polymerelectrolytes, solid or dry EC cells must be prepared from very thinfilms (e.g. total thickness of approximately 50 to 250 microns) tocompensate the lower conductivity with a high film contact surface,thereby providing electrochemical cells with high power density. Eachcomponent of the EC cells must therefore be produced into very thinfilms of about 5 to 125 microns each.

Pure solid lithium, or solid lithium having a small percentage of alloymetals, is so ductile that it can be easily cut and worked at roomtemperature. The production of the lithium metal thin film is usuallymade by an extrusion process wherein an ingot of lithium/lithium alloyis inserted into a cylinder and pressed or pushed by an extrusion stemthrough a die aperture of the desired shape and thickness. Thelithium/lithium alloy flows through a flow die of progressivelynarrowing cross-sectional area, thereby gradually shaping the metal flowtoward its final desired shape. The metal flow subsequently exitsthrough a flat faced die having an aperture featuring the desired crosssectional profile. In the particular case of a lithium metal anode, theprofile is a thin and substantially rectangular one. Because of therequirement that the cylindrical ingot which enters the flow die mustexit the latter as a thin film of substantially rectangular shape,manufacturers have to date been limited to produce lithium metal filmsof a width which does not exceed the diameter of the ingot itself. Thesize of the anodes so produced are therefore limited to the diameter ofcommercially available ingots.

The extrusion process of a lithium/lithium alloy ingot as describedabove must also be performed under vacuum since lithium is highlyreactive, and it therefore easily oxidizes when exposed to theatmosphere. This is especially the case when it is heated and underpressure. The process of pushing the ingot along the walls of thecylinder chamber under high pressure generates sufficient heat for thelithium to react with ambient nitrogen and form nitrides (i.e.,6Li+N2→2Li3N) so that the process must be performed under vacuum.However, when the ingot has been almost completely extruded and a newingot must be placed inside the cylindrical chamber, the chamber isopened thereby allowing ambient air to enter the chamber and react withthe hot lithium left along the chamber's walls. For that reason, thetypical lithium extrusion process includes the step of thoroughlycleaning the walls of the cylindrical chamber prior to extruding a newingot in order to remove all nitrides which remain thereon. Otherwise,traces of hard nitrides could block the die opening and cause a split inthe extruded lithium/lithium alloy sheet, thereby rendering the sheetunusable for the production of EC cell components.

Furthermore, the length of the lithium/lithium alloy film that can beproduced by the prior art extrusion process is limited by the amount ofmaterial contained in a single ingot. This is so due to the fact thatwhen a new ingot is placed inside the chamber, the remaining portion ofthe previous ingot (2–5 mm) must be removed since it cannot flowperpendicular to the pressure. Thus, the conventional lithium extrusionprocess produces a finite length of extruded lithium/lithium alloy sheetper ingot.

Considering this background, it clearly appears that there is a need fora process and apparatus adapted to produce a thin sheet or film oflithium/lithium alloy that alleviates the limitations imposed by thesize and length of commercially available lithium/lithium alloy ingots.

STATEMENT OF THE INVENTION

It is therefore an object of the present invention to provide a methodof extruding a lithium/lithium alloy ingot into a thin sheet or film ofa width not limited by the diameter of the ingot.

It is another object of the present invention to provide a method ofextruding lithium or lithium alloy into a thin sheet or film in asemi-continuous process.

It is a further object of the present invention to provide alithium/lithium alloy thin sheet film obtained from an extrusion processhaving a width exceeding the diameter of the original lithium/lithiumalloy ingot.

As embodied and broadly described, the invention provides a method ofextruding lithium or lithium alloy to form a thin sheet, the methodcomprising the steps of:

-   providing an ingot of lithium metal or lithium alloy having a length    and a diameter;-   pressing the ingot through a flow channel comprising an entrance    having a first height and a first width, an exit having a second    height and a second width and a passage joining the entrance and the    exit, the second width being larger than the first width such that    the lithium metal or lithium alloy exits the flow channel with a    overall width exceeding the diameter of the ingot; and thereafter,    extruding the lithium metal or lithium alloy through an extrusion    die aperture in the form of a thin sheet.

In a preferred embodiment, the extrusion die aperture is adjustable suchthat the height of a central portion of the die aperture may exceed theheight of both extremities of the die aperture.

As embodied and broadly described, the invention also provides a methodof extruding lithium or lithium alloy ingots to form a thin sheet,through an extrusion apparatus comprising an inner chamber, a pistonhead at one end of said inner chamber and a flow die and extrusion dieassembly at a second end of said chamber; the method comprising thesteps of:

-   inserting a first ingot of lithium metal or lithium alloy into the    inner chamber;-   creating partial vacuum inside the inner chamber, the partial vacuum    extending in front and behind the piston head;-   pressing the first ingot with the piston head through the flow die    and extrusion die assembly;-   when the first ingot is partially extruded, retrieving the piston    head while maintaining partial vacuum throughout the inner chamber;-   when the piston head is retrieved, opening a rear door of the    extrusion apparatus and inserting a second ingot of lithium metal or    lithium alloy into the inner chamber such that one end of the second    ingot abuts one end of the first ingot;-   pressing the second ingot with the piston head onto the first ingot    such that abutting ends of the first and second ingots fuse together    under the pressure applied by the piston head and a continuous    length of thin sheet of lithium or lithium alloy is extruded from    more that one ingot.

Advantageously, the piston head comprises a smooth substantially flatsurface such that when the piston head presses against the rear surfaceof the ingot, the rear surface of the ingot remains substantially smoothand flat thereby allowing fusion of the abutting ingots without voids.In a further embodiment, an adapter plate having a smooth substantiallyflat surface is positioned at the front of the piston head allowing astandard piston head to be adapted to the process.

As embodied and broadly described, the invention further provides anelectrochemical cell comprising a thin lithium metal anode sheet, acathode and an electrolyte separator between the anode and the cathode,the thin lithium metal anode sheet obtained by an extrusion process of alithium or lithium alloy ingot having a length and a diameter, the thinlithium metal anode sheet having a width exceeding the diameter of thelithium or lithium alloy ingot.

As embodied and broadly described, the invention also provides a dieassembly for use in extruding lithium or lithium alloy ingots into athin sheet, said die assembly comprising a die holder and an extrusiondie having an adjustable die aperture, said die holder having adjustmentmeans for adjusting said die aperture.

Advantageously, the extrusion die comprises an upper plate secured to alower plate together defining the extrusion die aperture, the upperplate and the lower plate comprising adjustment means for adjusting acurvature of the upper plate and lower plate, the die holder adjustmentmeans being connected to the upper plate and the lower plate adjustmentmeans when the extrusion die is positioned in the die holder such thatan operator may adjust the die aperture while extruding lithium orlithium alloy ingots.

BRIEF DESCRIPTION OF THE DRAWINGS

A detailed description of examples of implementation of the presentinvention is provided hereinbelow with reference to the followingdrawings, in which:

FIG. 1 is a schematic side cross-sectional drawing of an apparatus forforming a lithium/lithium alloy extrusion into a thin sheet inaccordance with one embodiment of the invention, the figure also showingthe metal flow during the extrusion process;

FIG. 2 is a schematic enlarged cross-sectional view of a flow die asshown in FIG. 1;

FIG. 2 a is a schematic top plan view of the channel of the flow dieshown in FIG. 2;

FIG. 2 b is a plan view of the entrance of the channel of the flow dieshown in FIG. 2;

FIG. 2 c is a plan view of the exit of the channel of the flow die shownin FIG. 2;

FIG. 3 is a rear exploded perspective view of an extrusion die as shownin FIG. 1;

FIG. 4 is a front elevational view of the extrusion die shown in FIG. 3,the extrusion die being assembled;

FIG. 5 is a rear perspective view of the extrusion die shown in FIG. 4;

FIG. 6 a is a perspective view of a die assembly in accordance with avariant; and

FIG. 6 b is a perspective exploded view of the die assembly shown inFIG. 6 a.

In the drawings, embodiments of the invention are illustrated by way ofexample. It is to be expressly understood that the description anddrawings are only for purposes of illustration and as an aid tounderstanding, and are not intended to be a definition of the limits ofthe invention.

DETAILED DESCRIPTION OF THE DRAWINGS

With reference to FIG. 1, there is shown an apparatus 10 for extrudingsolid lithium or alloys thereof. The apparatus 10 comprises a mainstructural body 12 having a front door 14 and a rear door 16 all made ofthick cast iron which is adapted to withstand the high pressures thatare generated within the extrusion apparatus 10. The structural body 12as well as the front and rear doors 14 and 16 together define acylindrical inner chamber 18. Inner chamber 18 comprises a 4140 steelsleeve 20 adapted to receive and accommodate a commercially availablelithium/lithium alloy ingot 22. Sleeve 20 may be removed from thestructural body 12 for cleaning and general maintenance. The rear door16 accommodates therethrough a piston 24 having a piston head 26 whichis adapted to reciprocate within inner chamber 18 and apply pressure tothe ingot 22. The piston head 26 comprises a front adapter plate 28having a smooth flat surface to apply an even pressure onto the ingotsuch that the rear surface of the ingot 22 remains perfectly smooth whenpiston 24 presses onto it during the extrusion process. The rear door 16further comprises a vacuum conduit 30 connected at one end to a vacuumpump (not shown) and at the other end to the rear portion 32 of innerchamber 18 such that the extrusion process is carried out under vacuumand the entire inner chamber 18 is under vacuum, including the rearportion 32 located behind piston head 26. The front door 14 comprises aninner housing adapted to receive an extrusion die 34, a separator plate36, and a flow die 38 assembly through which the ingot 22 is extrudedinto a thin sheet 40. The extruded thin sheet 40 is pulled and rolledunder a predetermined tension by and through a series of cylindricalrollers 42, as is well known in the art, and finally wound onto a roll44 for subsequent storage or further processing.

Referring to FIGS. 1 to 2 b, the extrusion process in accordance withthe invention is carried out as detailed hereinafter. Firstly, acommercially available pure lithium ingot 22 or alloy thereof having atypical length of 10, 15 or 30 inches and a typical diameter of 8 inchesis inserted through the opened rear door 16 into the inner chamber 18.Rear door 16 is then closed. A vacuum pump connected to the vacuumconduit 30 is subsequently activated to create a partial vacuum insideinner chamber 18 in front and behind of piston head 26. When apredetermined vacuum is established inside inner chamber 18, piston 24is activated. Piston 24 applies a high pressure P to the rear surface ofingot 22 forcing the lithium metal/lithium metal alloy through flow die38 (as illustrated by the series of arrows in FIG. 2), through separatorplate 36 which defines the final width of the thin lithium alloy sheet40, and finally through extrusion die 34. Pressure P typically variesbetween 100 and 500 tons depending on the modulus of elasticity of thelithium alloy; the latter being proportional to the percentage ofaluminum in the lithium alloy. The percentage of aluminum in the alloyincreases the minimum pressure necessary for extrusion of the ingot. Thelithium/lithium alloy flows though a channel of flow die 38 having an8-inch entrance and a 9 to 10 inch exit such that the width of theexiting lithium exceeds the diameter of the initial ingot 22. A thinsheet 40 of lithium/lithium alloy having a thickness of 150 microns to300 microns emerges from the extrusion die 34. As indicated previously,the thin lithium/lithium alloy sheet 40 is then pulled and rolled undera predetermined tension by cylindrical rollers 42 and wound onto a roll44 for storage or to be brought to a further processing station.

When a substantial portion of ingot 22 is extruded such that a fewinches of the initial ingot's length are left, piston 24 is pulled backwhile the vacuum is still maintained throughout inner chamber 18. Aspiston 24 is pulled back, the cylindrical sleeve 20, as well as anytraces of lithium left thereon, are allowed to sufficiently cool downsuch that the traces of lithium/lithium alloy will not react with theambient air when rear door 16 is opened. When piston 24 is fullyretrieved within a recess of rear door 16, the latter is opened and anew ingot is inserted into inner chamber 18; the front portion of thenew ingot abutting against the rear surface of the remaining ingot 22.Since piston head 26 is provided with a front adapter plate 28 having asmooth flat surface, the rear surface of the remaining ingot 22 is alsosmooth. As a result, when the front face of the new ingot abuts the rearsurface of the remaining ingot 22, there are no voids therebetween. Therear door 16 is then closed behind the new ingot, the vacuum pump isactivated to re-establish the partial vacuum inside inner chamber 18 infront and behind piston head 26. When the predetermined vacuum isreached, piston 24 then applies pressure onto the rear surface of thenew ingot. Since pure solid lithium or solid lithium having a smallpercentage of alloy metals are so ductile, when the front face of thenew ingot is pressed against the rear face of the remaining ingot, thetwo ingots fuse together via the action of the high pressure applied bypiston 24; the resulting lithium sheet 40 formed thereby may be extrudedalmost continuously (more precisely, the process is semi-continuous).Since some time is required to properly fuse the two ingots, theremaining few inches of the first ingot provide enough margin to ensurethat the two ingots will be fused when the abutting sections of thefused ingots reach the extrusion die 34.

The semi-continuous extrusion process described above has two distinctadvantages over the prior art methods. Firstly, it eliminates the wastedlithium/lithium alloy that usually occurs in conventional extrusionprocesses. When an ingot is nearly completely extruded in a conventionalprocess, the remaining portion or left over portion of the ingot leftagainst the extrusion die (which usually has a length of a fewmillimeters) must be discarded prior to inserting a new ingot. Secondly,in conventional lithium extrusion processes, the partial vacuum is lostwhen front door 14 is opened. When piston 24 is pulled back, the tracesof lithium left on the walls of sleeve 20 react with the ambient air toform nitrides. The sleeve 20 must therefore be thoroughly cleaned orreplaced with a new sleeve 20 prior to extruding a new ingot. Otherwise,traces of nitrides could be found in the extruded sheet, which would beunacceptable. Conventional lithium extrusion processes can only extrudelithium/lithium alloys in batches and cannot extrude an entire ingot, asthere is always an unused portion of the ingot (1 to 3 mm) left in theinner chamber when a new ingot must be inserted in the extruder. Thesemi-continuous lithium/lithium alloy extrusion process according to theinvention enables the extrusion of the entire length of the ingot andalso ensures that no traces of nitrides will block the extrusion die 34and slice the extruded sheet since a vacuum is maintained in front andbehind piston head 26 throughout the entire stroke of piston 24 and thetraces of lithium left along the wall of sleeve 20 are allowed to cooldown prior to opening rear door 16 thereby preventing the formation ofnitrides harmful to the extrusion process.

Referring now more specifically to FIGS. 2, 2 a, 2 b and 2 c whichillustrate flow die 38 and more specifically the flow die channel 50through which the lithium metal/lithium alloy metal flows and isfunneled towards extrusion die 34. As shown, flow die channel 50comprises an entrance 52, an exit 54, an upper wall 56, a lower wall 58,and a pair of side walls 60 and 62 which together define a passage forthe flow of lithium/lithium alloy metal. In this particular design,lower wall 58 is a mirror image of upper wall 56. The central portion 64of entrance 52 is about 0.3 to 0.5 inches in height and the full widthof entrance 52 is about 8 inches when extruding an ingot of 8-inchdiameter. The central portion 66 of exit 54 is about 0.1 to 0.2 inchesin height and the full width of exit 54 is about 9 to 10 inches whenextruding an ingot of 8-inch diameter. As shown in FIGS. 2 a, 2 b and 2c, the side portions 68 and 70 of channel 50 have larger cross-sectionalareas than the central portions 64 and 66 respectively and are designedto generate a substantially outward flow of metal away from the centralportions 64 and 66 and toward side walls 60 and 62 in order to expandthe width of the resulting sheet 40 such that the width of the latterexceeds the diameter of the initial ingot 22. The flow of metal isguided outwardly along the sidewalls 60 and 62 by the increasedcross-sectional areas of side portions 68 and 70, which are angledoutwardly. Side portions 68 and 70 further comprise sub-channels 72 and74 running along side walls 60 and 62 which are adapted to furthergenerate increased metal flow along side walls 60 and 62. The ductilityof lithium metal or alloys thereof is advantageously exploited bychannel 50 to guide the metal flow outwardly to obtain a sheet having awidth exceeding that of the ingot's initial diameter.

The lithium/lithium alloy metal exits flow die 38 with a profile whichcorresponds to that of exit 54, shown in detail in FIG. 2 c. Thelithium/lithium alloy metal then flows through a flat face extrusion die34 as illustrated in FIGS. 3 to 5 where its profile is further reducedto that of a thin sheet. As shown in FIG. 1, the flat face 83 of theflat face extrusion die 34 is facing the oncoming flow of metal.

Extrusion die 34 comprises an upper plate 76 and a lower plate 78together defining a die opening 80 in the form of a thin substantiallylinear aperture of about 10 thousandths of an inch (or roughly about 250microns) in height and of about 9 to 10 inches in width. Upper plate 76and lower plate 78 are machined from tungsten carbide and comprise apair of flat surfaces 82 and 84 located adjacent to die opening 80, andupon which plates 76 and 78 rest against one another. Die opening 80 isdefined by inserting between flat surfaces 82 and 84 a pair ofcalibrated shims 85 and 87 of the precise thickness of thelithium/lithium alloy sheet to be extruded. With a selected pair ofshims 85 and 87 installed, lips 81 form a thin die opening 80 of adesired dimension corresponding to the thickness of the extrudedlithium/lithium alloy sheet. Each plate 76 and 78 further comprisesinsteps 88 and 90 respectively located on the far side of each flatsurface 84 and 82. As shown in FIG. 4, when upper plate 76 and lowerplate 78 are assembled, insteps 88 and 90 define gaps 92 and 94 adjacenteach calibrated shim 85 and 87. A pair of threaded fasteners 86 extendsthrough each gap 92 and 94 and acts to primarily secure upper plate 76to lower plate 78 but also to provide adjustment means of the curvatureof the lips 81 to adjust the shape of die opening 80. When threadedfasteners 86 are tightened beyond a predetermined torque, fasteners 86close gaps 92 and 94 thereby leveraging the entire length of plates 76and 78 on calibrated shims 85 and 87 with the effect of marginallybending the entire length of lips 81 such that die opening 80 becomeseye-shaped with its center portion marginally more opened than itssides. The adjustment of the torque of threaded fasteners 86 enables tofine tune the final shape of the extruded lithium/lithium alloy thinsheet 40.

In the extrusion process of very thin lithium/lithium alloy sheets asdescribed herein, the central portion of the extruded thin sheet may bemarginally thinner than its edge portions due to pressure variationsalong the length of die opening 80. The adjustment of threaded fasteners86 provides means for adjusting the thickness of the central portion ofthe lithium/lithium alloy sheet 40 such that it is at least equal tothat of its edge portions. Although FIGS. 3 to 5 depict adjusting meansin the form of threaded fasteners 86, it should be expressly understoodthat any other type of adjusting means such as cam mechanisms, gearmechanisms, wedges, etc. remains within the scope of the presentinvention. Moreover, any number of threaded fasteners, alternativeadjusting means, or combinations thereof can also be used for a singleextrusion die.

In practice it is sometimes advantageous to extrude a thin sheet havinga central portion marginally thicker than its edge portion. Such is thecase, for example, when an extruded lithium/lithium alloy sheet having athickness of roughly 250 microns is further processed by lamination,rolling or calendaring in order to reduce its final thickness to lessthan 100 microns and more preferably less than 50 microns. If theextruded lithium/lithium alloy sheet features a marginally thickercentral portion, the pressure rollers used in the thickness reductionoperations will therefore always be in contact with at least the centralportion of the sheet and may work the latter to an even thicknesswithout creating sunken areas.

Although the process and apparatus (i.e., extrusion die and the like)described and depicted herein are designed for the extrusion of acylindrical ingot having an initial diameter of approximately 8 inches,it should be understood that the present invention also contemplates theextrusion of ingots of any other dimension and shape. Moreover, theprocess and apparatus disclosed herein have been described in connectionwith an ingot composed of lithium or an alloy thereof. It should beexpressly understood, however, that the use of alternative materialswhich are suitable for use as anode components and which exhibit thedesired properties (e.g., ductility and the like) remains within thescope of the present invention.

As illustrated in FIGS. 6 a and 6 b, in a variant, the extrusionapparatus can further comprise a die holder 100 adapted to receive,support and align extrusion die 34, separator plate 36, and flow die 38.Die holder 100 comprises a first recessed portion 102 adapted to houseextrusion die 34 and a second recessed portion 104 adapted to houseseparator plate 36 and flow die 38. Separator plate 36 and flow die 38are preferably aligned with extrusion die 34 using guide pins 107 suchthat flow channel 50, separator plate opening 106 and extrusion dieopening 80 are in alignment to provide reproducibility of process. Flowdie 38 is secured to die holder 100 with a series of fasteners 108. Dieholder 100 is further provided with a set of adjustment channels 110 and112. Channels 110 are located on either side of die holder 100 (althoughonly one is shown in the Figures) and give access to the threadedfasteners 86 of extrusion die 34 such that the curvature of die opening80 may be adjusted when extrusion die 34 is installed in die holder 100.Channels 112 are located in the central portion of die holder 100 andgive access to one or more threaded fasteners positioned along thelength of extrusion die 34 to provide fine tuning of die opening 80. Inone embodiment, there is provided a single adjustment fastener 115located in the middle of die opening 80 to provide a means of adjustingthe central portion of die opening 80. In a second embodiment (as shown)three adjustment fasteners 114 and 115 are positioned along the lengthof die opening 80 to provide means of adjusting the side portions andthe central portion of die opening 80. Any number of adjustmentfasteners, however, may be used without departing from the spirit of theinvention. Advantageously, either the front door 14 onto which dieholder 100 is mounted or the structural body 12 of extrusion apparatus10 are provided with means of reaching the adjustment fasteners 86, 114and 115 when die holder 100 is positioned inside extrusion apparatus 10such that adjustment and fine tuning of die opening 80 may be carriedout during the extrusion process. As shown in the embodiment of FIGS. 6a and 6 b, die holder 100 can, for example, be mounted onto a flat frontdoor 118 with fasteners 119 and the structural body 12 of extrusionapparatus 10 is provided with a series of apertures aligned withchannels 110 and 112 of die holder 100 when front door 118 is closed. Inanother embodiment not shown, die holder 100 can be mounted into arecess of front door 118 and a series of apertures aligned with channels110 and 112 are provided in door 118 to reach the adjustment fastenersand allow adjustment and fine tuning of die opening 80 during theextrusion process. Other means of adjusting and fine tuning die opening80 during the extrusion process are also contemplated without departingfrom the invention. For example, long fasteners may be used to avoid theneed of using long tools to access fasteners 86, 114 and 115. As well,various extensions may be built into front door 118 or the structuralbody 12 of extrusion apparatus 10 that engage the various adjustmentfasteners when die holder 100 is installed. Furthermore, die holder 100may be provided with built-in adjustment means, which mate with variousextensions built into front door 118 or the structural body 12 ofextrusion apparatus 10. Various other embodiments and configurations arecontemplated to allow adjustment and fine tuning of die opening 80during the extrusion process.

Although the present invention has been described in relation toparticular variations thereof, other variation and modifications arecontemplated and are within the scope of the present invention.Therefore the present invention is not to be limited by the abovedescription but is defined by the appended claims.

1. A die assembly for use in extruding a lithium or lithium alloy ingotinto a thin sheet, said die assembly comprising: a die holder; and anextrusion die positioned in said die holder, said extrusion die having afirst plate and a second plate defining a substantially linear dieaperture, said die holder having adjustment means connected to saidfirst and second plate for adjusting a curvature of each said first andsecond plate to thereby adjust a profile of said die aperture.
 2. A dieassembly as defined in claim 1, wherein said adjustment means connectedto said first plate and said second plate are accessible when saidextrusion die is positioned in said die holder such that an operator mayadjust said die aperture while extruding lithium or lithium alloyingots.
 3. A die assembly as defined in claim 1, further comprising aflow die positioned upstream of said extrusion die, said flow die havinga flow die channel including an entrance having a first height and afirst width, an exit having a second height and a second widths and apassage joining said entrance and said exit, said second width beingwider than said first width and being wider than a diameter of an ingotto be extruded such that said lithium or lithium alloy exits said flowdie channel with an overall width exceeding the diameter of the ingot.4. A die assembly as defined in claim 3, wherein said passage comprisesa top wall, a bottom wall and a pair of side walls connecting said topwall and said bottom wall, and a sub channel of increasedcross-sectional area running along each said side wall, said sub channeladapted to increase the flow of metal along each said side wall.
 5. Adie assembly as defined in claim 3, further comprising a separator platepositioned between said flow die and said extrusion die, said separatorplate having an aperture of precise width for controlling the width of alithium or lithium alloy thin sheet being extruded.
 6. A die assembly asdefined in claim 1, wherein said die aperture has a height of about 250microns or less.
 7. An extrusion die for use in extruding a lithium orlithium alloy ingot into a thin sheet, said extrusion die comprising: afirst plate and a second plate together defining a substantially lineardie aperture having a profile; and adjustment means connected to atleast one of said first plate and said second plate for adjusting acurvature of each one of the at least one of said first plate and saidsecond plate to thereby adjust the profile of said die aperture.
 8. Anextrusion die as defined in claim 7, wherein said adjustment meansincludes at least one threaded fastener interconnecting said first plateand said second plate.
 9. An extrusion die as defined in claim 7,wherein said adjustment means acts on the at least one of said firstplate and said second plate on both sides of said die aperture.
 10. Anextrusion die as defined in claim 7, wherein said die aperture has aheight of about 250 microns or less.
 11. A die assembly for use inextruding a lithium or lithium alloy ingot into a thin sheet, said dieassembly comprising: an extrusion die having a die aperture; and a flowdie positioned upstream of said extrusion die, said flow die having aflow die channel including: an entrance having a first height and afirst width; an exit having a second height and a second width; and apassage joining said entrance and said exit; said second width beingwider than said first width and being wider than a diameter of an ingotto be extruded such that the lithium or lithium alloy exits said flowdie channel with an overall width exceeding the diameter of the ingot.12. A die assembly as defined in claim 11, wherein said passagecomprises a top wall, a bottom wall and a pair of side walls connectingsaid top wall and said bottom wall, and a sub channel of increasedcross-sectional area running along each said side wall, said sub channeladapted to increase the flow of metal along each said side wall.
 13. Adie assembly as defined in claim 11, further comprising a separatorplate positioned between said flow die and said extrusion die, saidseparator plate having an aperture of precise width for controlling thewidth of a lithium or lithium alloy thin sheet being extruded.
 14. A dieassembly as defined in claim 11, wherein said die aperture has a heightof about 250 microns or less.